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Department of Chemistry and Chemical Biology | G. Charles Dismukes
Department of Chemistry & Chemical Biology | Rutgers, The State University of New Jersey

G. Charles Dismukes

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G. Charles Dismukes - Research

2025 Research programs

Use this link to download 2025-Research programs in Charles Dismukes Research Group

Annual Research Reports

2023-2024 Annual Research Report

Earth-abundant catalysts for the Hydrogen Evolution Reaction (HER) (2)

Ni5P4 HERHydrogen is a bulk chemical produced on the 107 ton/year scale but could also be a fuel of the future. Today this hydrogen is produced from methane in steam reforming. Switching the hydrogen production to a renewable resource is a challenge, but some electrolyzers produce hydrogen on a commercial scale already from electricity (electrochemically). We are developing hydrogen evolution catalysts for benign neutral conditions in order to reduce hydrogen costs to a level competitive with conventional fuels.

Read more …

Photoelectrochemical water-splitting (PEC)

PEC

 

Photoelectrochemical cells (PEC) that can split water into hydrogen and oxygen using sunlight are a promising strategy to generate and store clean, renewable energy. However, PEC devices suffer from low stability and efficiency, preventing them to penetrate the market. Our group aims to significantly increase the solar to hydrogen conversion efficiency up to 10% using a tandem configuration, as well as to increase the lifetime of the device. In a tandem device, two semiconductor light absorbers (one for high energy and one for low energy radiation) are combined to utilize most of the solar spectrum. We are also interfacing the photoabsorbers with Rutgers-developed best in class earth-abundant hydrogen and oxygen-evolving catalysts to decrease the required cell potential to drive water splitting.

 

Read more …

  1. Earth-abundant catalysts for the Carbon Dioxide Reduction Reaction
  2. Perovskite-based oxyhydrides as nitrogen fixation catalysts
  3. Heterogeneous Water Oxidizing Catalysts from Inert Transition Metal Oxide Spinels
  4. Molecular Catalysts for Water Oxidation

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